EEENS - SDS(TM) SILICON TETRAFLUORIDE
- MSDS: EEENS
- Manufacturer: MATHESON TRI GAS INC
- Product Name: SDS(TM) SILICON TETRAFLUORIDE
- National Stock Number: -
Product Identification
Product ID:SDS(TM) SILICON TETRAFLUORIDE
MSDS Date:Mar 31 1998
MSDS Number: EEENS
Kit Part:=== Responsible Party ===
Company Name:MATHESON TRI-GAS, INC.
Address:959 ROUTE 46 EAST
City:PARSIPPANY
State:NJ
ZIP:07054-0624
Country:US
Info Phone Num:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON)
780-471-4036
Chemtrec Ind/Phone:18004249300
Contractor
Telephone: (USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON)
Ingredients
SILICON TETRAFLUORIDE
CAS: 7783-61-1
Fraction By Weight: >99.9%
PROPRIETARY SORBENT
Fraction By Weight: <1%
Hazards
Reports of Carcinogenicity:NTP:No IARC:No OSHA:No
Health Hazards Acute and Chronic:INHALATION: SHORT TERM EXPOSURE: burns
LONG TERM EXPOSURE: same as effects reported in short term exposure
SKIN CONTACT: SHORT TERM EXPOSURE: burns LONG TERM EXPOSURE: same
as effects reported in short term exposure EYE CONTACT: SHORT TERM
EXPOSURE: burns LONG TERM EXPOSURE: same as effects reported in
short term exposure INGESTION: SHORT TERM EXPOSURE: ingestion of
harmful amounts is unlikely LONG TERM EXPOSURE: ingestion of
harmful amounts is unlikely
Medical Cond Aggravated by Exposure:
First Aid
First Aid: INHALATION: If adverse effects occur, remove to
uncontaminated area. Give artificial respiration if not breathing.
If breathing is difficult, oxygen should be administered by
qualified personnel. Get immediate medical attention. SKIN CONTACT:
Wash skin with soap and water for at least 15 minutes while
removing contaminated clothing and shoes. Get immediate medical
attention. Thoroughly clean and dry contaminated clothing and shoes
before reuse. Destroy contaminated shoes. EYE CONTACT: Immediately
flush eyes with plenty of water for at least 15 minutes. Then get
immediate medical attention. INGESTION: If a large amount is
swallowed, get medical attention.
Fire Fighting
Flash Point:not flammable
Extinguishing Media:carbon dioxide, regular dry chemical Large fires:
Use regular foam or flood with fine water spray.
Fire Fighting Procedures:Move container from fire area if it can be
done without risk. Cool containers with water spray until well
after the fire is out. Stay away from the ends of tanks. Keep
unnecessary people away, isolate hazard area and deny entry.
Unusual Fire/Explosion Hazard:Negligible fire hazard.
Accidental Release
Spill Release Procedures:Stop leak if possible without personal risk.
Reduce vapors with water spray. Do not get water directly on
material. Keep unnecessary people away, isolate hazard area and
deny entry. Stay upwind and keep out of low areas. Ventilate closed
spaces before entering. Evacuation radius: 150 feet.
Neutralizing Agent:
Handling
Handling and Storage Precautions:Store and handle in accordance with
all current regulations and standards. Store below 52 C. Store in a
cool, dry place. Store in a well-ventilated area. Subject to
storage regulations: U.S. OSHA 29 CFR 1910.101. See original
container for storage recommendations. Keep separated from
incompatible substances.
Other Precautions:
Exposure Controls
Respiratory Protection:No respirator is required under normal
conditions of use. Under conditions of frequent use or heavy
exposure, respiratory protection may be needed. For Unknown
Concentrations or Immediately Dangerous to Life or Health - Any
supplied-air respirator with full facepiece and operated in a
pressure-demand or other positive-pressure mode in combination with
a separate escape supply. Any self-contained breathing apparatus
with a full facepiece.
Ventilation:Provide local exhaust or process enclosure ventilation
system. Ensure compliance with applicable exposure limits.
Protective Gloves:Wear appropriate chemical resistant gloves.
Eye Protection:Wear splash resistant safety goggles with a faceshield.
Provide an emergency eye wash fountain and quick drench shower in
the immediate work area.
Other Protective Equipment:Wear appropriate chemical resistant
clothing.
Supplemental Safety and Health
SILICON TETRAFLUORIDE: INORGANIC FLUORIDES (as F): 2.5 mg/m3 OSHA TWA
2.5 mg/m3 ACGIH TWA 2.5 mg/m3 NIOSH recommended TWA 10 hour(s)
Chemical Properties
Boiling Pt:-123 F (-86 C)
Melt/Freeze Pt:-130 F (-90 C)
Vapor Pres:Not available
Vapor Density:3.63
Spec Gravity:1.7 @ -95 C
pH:acidic in solution
Evaporation Rate & Reference:Not applicable
Solubility in Water:decomposes
Appearance and Odor:PHYSICAL STATE:gas COLOR:colorless ODOR:irritating
odor
Corrosion Rate:
Stability
Stability Indicator/Materials to Avoid:May react with evolution of heat
on contact with water. Releases toxic, corrosive, flammable or
explosive gases.
Stability Condition to Avoid:Minimize contact with material. Containers
may rupture or explode if exposed to heat.
Hazardous Decomposition Products:Thermal decomposition products: acid
halides Thermal decomposition products: acid halides
Conditions to Avoid Polymerization:Will not polymerize.
Disposal
Waste Disposal Methods:Dispose in accordance with all applicable
regulations.
Toxicology
Toxicological Information:SILICON TETRAFLUORIDE: TOXICITY DATA: 2272
ppm inhalation-rat LC50 LOCAL EFFECTS: Corrosive: inhalation, skin,
eye, ingestion ACUTE TOXICITY LEVEL: Moderately Toxic: inhalation
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: central nervous system
disorders, bone, joint or tooth disorders, eye disorders, kidney
disorders, respiratory disorders, skin disorders and allergies
ADDITIONAL DATA: May cross the placenta. May be excreted in breast
milk.
Other Information
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ecology
Ecological:Not available
Transport
Transport Information:U.S. DOT 49 CFR 172.101: PROPER SHIPPING NAME:
Silicon tetrafluoride, compressed ID NUMBER: UN1859 HAZARD CLASS OR
DIVISION: 2.3 LABELING REQUIREMENTS: Poison gas; Corrosive QUANTITY
LIMITATIONS: PASSENGER AIRCRAFT OR RAILCAR: Forbidden CARGO
AIRCRAFT ONLY: Forbidden
Regulatory
SARA Title III Information: SARA TITLE III SECTION 302 EXTREMELY
HAZARDOUS SUBSTANCES (40 CFR 355.30): Not regulated. SARA TITLE
III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.40): Not
regulated. SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS
CATEGORIES (40 CFR 370.21): ACUTE: Yes CHRONIC: No FIRE: No
REACTIVE: Yes SUDDEN RELEASE: Yes SARA TITLE III SECTION 313 (40
CFR 372.65): Not regulated.
Federal Regulatory Information:CERCLA SECTIONS 102a/103 HAZARDOUS
SUBSTANCES (40 CFR 302.4): Not regulated. OSHA PROCESS SAFETY
(29CFR1910.119): Not regulated.
State Regulatory Information: California Proposition 65: Not regulated.